Simultaneous voltammetric determination of dypirone and paracetamol with carbon paste electrode and multivariate calibration methodology
نویسندگان
چکیده
منابع مشابه
Simultaneous Voltammetric Determination of Dypirone and Paracetamol with Carbon Paste Electrode and Multivariate Calibration Methodology
Esse artigo descreve a determinação simultânea de dipirona (DIP) e de paracetamol (PAR) utilizando a técnica de Voltametria de Pulso Diferencial (VPD) e eletrodo de pasta de carbono não modificado. Devido à sobreposição dos picos voltamétricos de DIP e PAR, a metodologia de calibração multivariada baseada na Regressão de Mínimos Quadrados Parciais (PLSR) foi proposta. O conjunto de voltamograma...
متن کاملSimultaneous Voltammetric Determination of Dopamine and Ascorbic Acid using Multivariate Calibration Methodology Performed on a Carbon Paste Electrode Modified by a mer-[RuCl3(dppb)(4-pic)] Complex
A preparação e caracterização eletroquímica do eletrodo de pasta de carbono (EPC) modificado com o mer-[RuCl 3 (dppb)(4-pic)] (dppb= Ph 2 P(CH 2 ) 4 PPh 2 , 4-pic= CH 3 C 5 H 4 N), denominado Rupic, foi investigada. O sistema EPC/Rupic apresentou apenas um par de picos com potencial médio de 0,28 V vs. Ag/AgCl, o qual foi atribuído ao processo de transferência de elétrons do Ru/Ru. Este eletrod...
متن کاملSimultaneous Voltammetric Determination of Ascorbic Acid and Uric Acid Using a Modified Multiwalled Carbon Nanotube Paste Electrode
This paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (VI) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (AA). The electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (CV) that showed a shift of the oxidation peak potential of AA about 235 mV ...
متن کاملVoltammetric determination of cysteine at a carbon paste electrode modified with Cu(II)-salen complex
The electrochemical behavior of a modified carbon paste electrode (MCPE) with N,N′ethylenbis(salicylideneiminato)copper(II) complex ([Cu(II)-Salen]) was investigated as a newsensor for cystein. The Britton-Robinson buffer with pH 5, 10% modifier in electrode, potentialscanning rate of 20 mVs-1 and puls height of 50 mV were used as the optimum condition for thedetermination of cysteine using car...
متن کاملSimultaneous Determination of Ascorbic Acid, Uric Acid and Tryptophan by Novel Carbon Nanotube Paste Electrode
In the present paper, electrochemical methods were used to investigate the behavior of ascorbic acid at a carbon paste electrode modified with 2,2'-((1E)-(1,2 phenylenebis(azanylylidene)) bis(methanylylidene))bis(benzene-1,4-diol) (PBD) and oxidized multiwall carbon nanotubes. The modified carbon paste electrode showed high electrocatalytic activity toward ascorbic acid; the current was enhance...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2008
ISSN: 0103-5053
DOI: 10.1590/s0103-50532008000400021